The Franck-Condon Principle and Its Application to Crystals.
Franck-Condon Principle Using the Franck-Condon principle, we are able to calculate the intensities of transitions between vibrational states of the electronic energy levels. Due to their low mass, electron movement is fast compare with the nuclear movement and we can consider these two movements separately. Particularly, the position of.
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The theory is based on the Franck-Condon principle, which states that at the moment of the electron transfer no electron structure adjustment is possible because the reaction time is many magnitudes smaller than the time necessary for structural adjustment. This was combined with the previously known chemical reaction energy barrier.
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